J. Tully, E. Braxton, S. Cobb, B. Breeze, M. Markham, M. Newton, P. Rodriguez, J. Macpherson. Diamond Membrane Production: The Critical Role of Radicals in the Non-Contact Electrochemical Etching of sp2 Carbon. DOI: 10.33774/chemrxiv-2021-bjvn9

Y Pu, V Celorrio, JM Stockmann, O Sobol, Z Sun, W Wang, MJ Lawrence, J. Radnik, A. E Russell, V-D. Hodoroaba, L.Huang, P.Rodriguez .Surface galvanic formation of Co-OH on Birnessite and its catalytic activity for the oxygen evolution reaction J.of Catalysis 396,2021, 304-314

E.Sargeant, F. Illas, P. Rodríguez, F. Calle-Vallejo. Importance of the gas-phase error correction for O2 when using DFT to model the oxygen reduction and evolution reactions. J. Electroanal.Chem.896,  2021, 115178



E Sargeant, A Kolodziej, CS Le Duff, P Rodriguez. Electrochemical Conversion of CO2 and CH4 at Subzero Temperatures. ACS Catalysis 10, 2020, 7464

Y Pu, MJ Lawrence, V Celorrio, Q Wang, M Gu, Z Sun, LA Jácome, A. E Russell, L. Huang, P.Rodriguez. Nickel confined in 2D earth-abundant oxide layers for highly efficient and durable oxygen evolution catalysts. Journal of Materials Chemistry A 8,2020, 13340

N Awais, P Rodriguez, T Albrecht. Surface Design: Exploiting the Instability of Small Nanoparticles on Metallic Substrates. ECS Transactions 97,2020, 885

P Rodriguez, J Solla-Gullón. Electrocatalysis on Shape-Controlled Nanoparticles Frontiers in Chemistry 7,2020, 885


RK Raju, P Rodriguez, RL Johnston. Can a Single Valence Electron Alter the Electrocatalytic Activity and Selectivity for CO2 Reduction at the Subnanometre Level?. J.PhysChem C. 2019, DOI:10.1021/acs.jpcc.9b04745

Yayun Pu, Qianwen Chen, Zongzhao Sun, Paramaconi Rodriguez, Limin Huang. Anomalous phase transition of layered lepidocrocite titania nanosheets to anatase and rutile. Crystal Growth & Design 2019, DOI: 10.1021/acs.cgd.9b00147

Yvonne Grunder, Jack Beane, Adam Kolodziej, Christopher A Lucas, Paramaconi Rodriguez.Potential Dependent Structure and Stability of Cu (111) in Neutral Phosphate Electrolyte.Surfaces 2, 2019, 145-158



M. J Lawrence, V.Celorrio, X. Shi, Q. Wang, A.Yanson, N.J.E. Adkins, M. Gu, J. Rodríguez-López, P. Rodriguez.Electrochemical Synthesis of Nanostructured Metal-Doped Titanates and Investigation of Their Activity as Oxygen Evolution Photoanodes. ACS Applied Energy Materials 1,2018, 5233-5244

Q. Wang, Z.L.Zhao, S. Dong, D. He, M. J. Lawrence, S. Han, C.Cai, S. Xiang, P. Rodriguez, B. Xiang, Z. Wang, Y. Liang, M. Gu. Design of active nickel single-atom decorated MoS2 as a pH-universal catalyst for hydrogen evolution reaction. Nano Energy 53, 2018, 458-467.


Chang-Hui Chen, Colin Brennan, Stanley CS Lai, David J Fermin, Patrick R Unwin, Paramaconi Rodriguez.Adsorption and Electrochemical Oxidation of Small Sulfur− Containing Anions on Pt Electrodes in Organic Media. ChemElectroChem 5,2018, 2228-2234.

A Kolodziej, F Fernandez-Trillo, P Rodriguez. Determining the parameters governing the electrochemical stability of thiols and disulfides self-assembled monolayer on gold electrodes in physiological medium J. of Electroanal. Chem.819,2018, 51-57


Chang-Hui Chen, Adam Halford, Marc Walker, Colin Brennan, Stanley CS Lai, David J Fermin, Patrick R Unwin, Paramaconi Rodriguez.

Electrochemical characterization and regeneration of sulfur poisoned Pt catalysts in aqueous media. J. of Electroanal. Chem 816, 2018, 138-148.

A.Kolodziej, A.Cuesta and P.Rodriguez. “Single-Crystal surfaces as model electrocatalysts for CO2 reduction”. In: Electrochemical Reduction of

Carbon Dioxide: Overcoming the Limitations of Photosynthesis. Volume 21 of Energy and Environment.UK, RSC, 2018.

Matthew J Lawrence, Adam Kolodziej, Paramaconi Rodriguez. Controllable synthesis of nanostructured metal oxide and oxyhydroxide materials via electrochemical methods.Current Opinion in Electrochemistry 10, 2018, 7-15.

T Albrecht, S Horswell, LK Allerston, NV Rees, P Rodriguez. Electrochemical processes at the nanoscale. Current Opinion in Electrochemistry 7, 138-145



M.L Kromer, J. Monzo, M. J. Lawrence, A.Kolodziej, Z.T Gossage, B. H Simpson, S. Morandi, A.Yanson, J.Rodríguez-López, P.Rodríguez.High-Throughput Preparation of Metal Oxide Nanocrystals by Cathodic Corrosion and Their Use as Active Photocatalysts. Langmuir 33,2017, 13295.


CS Le Duff, MJ Lawrence, P Rodriguez. Role of the Adsorbed Oxygen Species in the Selective Electrochemical Reduction of CO2 to Alcohols and Carbonyls on Copper Electrodes. Angew. Chem.Int Ed. 129 ,2017, 13099.


Adam Kolodziej M. C. Figueiredo, M. T.M. Koper, Francisco Fernandez-Trillo, Paramaconi Rodriguez. Phosphate-mediated electrochemical adsorption of cisplatin on gold electrodes. Electrochim. Acta 248, 2017, 409



F.Monzo, D. van der Vliet, A.Yanson and P. Rodriguez. Elucidating the degradation mechanism of the cathode catalyst of PEFCs by a combination of electrochemical methods and X-ray fluorescence spectroscopy. PCCP 2016, 18, 22407 - 22415


E. Bennett, J. Monzó, J.J.L. Humphrey, D. Plana, M. Walker, C. Francis McConville, D.J. Fermin, A.Yanson and P.Rodriguez. A Synthetic Route for an Effective Preparation of Metal Alloy Nanoparticles and Its Use as Active Electrocatalyst. ACS Catalysis 6, 2016, 1533.


J.J.L. Humphrey, D. Plana, V. Celorrio, S. Sadasivan, R.P. Tooze, P. Rodríguez and D. J. Fermín. Electrochemical reduction of carbon dioxide at gold‐palladium core–shell nanoparticles: product distribution versus shell thickness. ChemCatChem 8, 2016, 952.


J. Monzó, Y. Malewski, R. Kortlever, F.J. Vidal‐Iglesias, J. Solla‐Gullon, M.T.M. Koper, P. Rodriguez. Enhanced electrocatalytic activity of Au@ Cu core@ shell nanoparticles towards CO 2 reduction. J. Mater. Chem. A., 3, 2015, 23690.


J. Monzó, Y. Malewski, F.J. Vidal‐Iglesias, J. Solla‐Gullon, P. Rodriguez. Electrochemical oxidation of small organic molecules on Au nanoparticles with preferential surface orientation. ChemElectroChem, 2, 2015, 958.

Wei Liu, Anne-Kristin Herrmann, Nadja C Bigall, Paramaconi Rodriguez, Dan Wen, Mehtap Oezaslan, Thomas J Schmidt, Nikolai Gaponik, Alexander Eychmüller. Noble Metal Aerogels: Synthesis, Characterization, and Application as Electrocatalysts. Accounts of chemical research 48, 2015, 154.

J Monzó, I Insua, F Fernandez-Trillo, P Rodriguez. Fundamentals, achievements and challenges in the electrochemical sensing of pathogens

Analyst 140 (21), 7116.

P. Rodriguez, N. Garcia-Araez, E. Herrero and J. Feliu. New insight on the behavior of the irreversible adsorption and underpotential deposition of thallium on platinum (111) and vicinal surfaces in acid electrolytes. Electrochim. Acta, 151, 2015, 319


G. Garcia, C. Stoffelsma, P. Rodriguez and M.T.M. Koper. Influence of beryllium cations on the electrochemical oxidation of methanol on stepped platinum surfaces in alkaline solution. Surface Science, 631, 2015, 267.


P.Rodriguez, D.Plana, D.J. Fermin and M.T.M. Koper.  New insights into the catalytic activity of gold nanoparticles for CO oxidation in electrochemical media. Journal of Catalysis 311, 2014, 182.


M. Duca, P. Rodriguez, A.Yanson and M.T.M. Koper. Selective electrocatalysis on platinum nanoparticles with preferential (100) orientation prepared by cathodic corrosion. Topics in Catalysis, 57, 2014, 255.

P. Rodriguez and T.J. Schmidt. “Platinum-Based Anode Catalysts for Polymer Electrolyte Fuel Cells.”In: Encyclopedia of Applied Electrochemistry.

New York: Springer, 2014.

P Rodriguez, MTM Koper. Electrocatalysis on gold. Physical Chemistry Chemical Physics 16, 2014, 13583-13594


W.Liu, P. Rodriguez, L.Borchardt, A.Foelske, J.Yuan, A-K.Herrmann, D. Geiger, Z. Zheng, S. Kaskel, N.Gaponik, R. Kötz, T.J. Schmidt and A. Eychmüller. Bimetallic Aerogels: High‐Performance Electrocatalysts for the Oxygen Reduction Reaction. Angew. Chem. Int. Ed, 52, 2013, 9849.


A.I. Yanson, P.V. Antonov, P. Rodriguez and M.T.M. Koper.Influence of the electrolyte concentration on the size and shape of platinum nanoparticles synthesized by cathodic corrosion. Electrochim. Acta, 112, 2013, 913.


Patent: High surface area catalyst for electrochemical processes and manufacture method, EP12177908201.


A Rabis, P Rodriguez, TJ Schmidt. Electrocatalysis for polymer electrolyte fuel cells: recent achievements and future challenges. ACS Catalysis 2, 2012, 864-890

Y. Kwon, Y. Birdja, I. Spanos, P. Rodriguez and M.T.M. Koper. Highly selective electro-oxidation of glycerol to dihydroxyacetone on platinum in the presence of bismuth. ACS Catal., 2, 2012, 759

N.Garcia-Araez, P.Rodriguez, H.J. Bakker and M.T.M. Koper. Effect of the surface structure of gold electrodes on the coadsorption of water and anions. J. Phys. Chem. C., 116, 2012, 4786.


J. Monzo, M.T.M Koper and P. Rodriguez. Removing polyvinylpyrrolidone from catalytic Pt nanoparticles without modification of superficial order. ChemPhysChem 13, 2012, 709.


P. Rodriguez, Y. Kwon and M.T.M. Koper, The promoting effect of adsorbed carbon monoxide on the oxidation of alcohols on a gold catalyst. Nature Chemistry, 4, 2012, 177.

Patent: Process to prepare metal nanoparticles or metal oxide nanoparticles, WO 2012010501.


N.Garcia-Araez, P.Rodriguez, V.Navarro, H.J. Bakker and M.T.M. Koper. Structural effects on water adsorption on gold electrodesJ. Phys. Chem. C., 115, 2011, 21249.


P. Rodriguez, F.D. Tichelaar,M.T.M. Koper and A.I. Yanson, .Cathodic corrosion as a facile and effective method to prepare clean metal alloy nanoparticles JACS 2011, 133 (44), 17626.


M.Duca, M. C. Figueiredo, V.Climent, P.Rodriguez, J.M. Feliu and M.T.M. Koper. Selective Catalytic Reduction at Quasi-Perfect Pt(100) Domains: A Universal Low-Temperature Pathway from Nitrite to N2. JACS 133, 2011, 10928.


D. Plana, P.Rodriguez, M.T.M. Koper and R. A.W. Dryfe.The electro-oxidation of dimethylamine borane: Part 2, in situ FTIR on single-crystal gold electrodes  Electrochimica Acta 56, 2011, 7637.


Y. Kwon, S.C.S. Lai, P. Rodriguez and M.T.M. Koper. Electrocatalytic oxidation of alcohols on gold in alkaline media: base or gold catalysis?. JACS 133, 2011, 6914.


A.I. Yanson, P. Rodriguez, N. Garcia-Araez, R.V. Mom, F.D. Tichelaar and M.T.M. Koper. Cathodic corrosion: a quick, clean, and versatile method for the synthesis of metallic nanoparticles. Angewandte Chemie Int. Ed. 50, 2011, 6346.


P. Rodriguez, G. Garcia, E. Herrero, J.M. Feliu and M.T.M. Koper. Effect of the surface structure of Pt (100) and Pt (110) on the oxidation of carbon monoxide in alkaline solution: an FTIR and Electrochemical study. Electrocatalysis 2 , 2011, 242.


M. Duca, M. Oroval Cucarella, P. Rodriguez and M.T.M. Koper. Direct reduction of nitrite to N2 on a Pt (100) electrode in alkaline media. JACS 132, 2010, 18042.


C. Stoffelsma, P. Rodriguez, G. Garcia, N. Garcia-Araez, D. Strmcnik, N. Markovic and M.T.M. Koper. Promotion of the oxidation of carbon monoxide at stepped platinum single-crystal electrodes in alkaline media by lithium and beryllium cations. JACS132, 2010, 16127.


N. Garcia-Araez, V. Climent, P. Rodriguez and J.M. Feliu.Thermodynamic evidence for K+ –SO4 2− ion pair formation on Pt (111). New insight into cation specific adsorption. PCCP 12, 2010, 12146.

N. Garcia-Araez, V. Climent, P. Rodriguez and J.M. Feliu. Elucidation of the Chemical Nature of Adsorbed Species for Pt(111) in H2SO4 Solutions by Thermodynamic Analysis. Langmuir 26, 2010, 12408.


P. Rodríguez, N. García-Aráez, A.A. Koverga, S. Frank and M.T.M. Koper. CO electroxidation on gold in alkaline media: a combined electrochemical, spectroscopic, and DFT study. Langmuir 26, 2010, 12425.


P. Rodríguez, N. García-Aráez and M.T.M. Koper. Self-promotion mechanism for CO electrooxidation on gold: a combined electrochemical, spectroscopic and DFT study. PCCP 12, 2010, 9373.


P. Rodríguez, A.A. Koverga, and M.T.M. Koper. Carbon monoxide as a promoter for its own oxidation on a gold electrode. Angewandte Chemie Int. Ed. 49, 2010, 1241.


S.C.S. Lai, S.E.F. Kleijn, F.T.Z. Öztürk, V.C. van Rees Vellinga, J. Koning, P. Rodríguez and M.T.M. Koper. Effects of electrolyte pH and composition on the ethanol electro-oxidation reaction. Catalysis Today 154, 2010, 92.


M. Duca, V. Kavvadia, P. Rodriguez and M.T.M Koper. New insights into the mechanism of nitrite reduction on a platinum electrode. J. Electroanal. Chem., 649, 2010, 59.


G. Garcia, P. Rodriguez, V. Rosca and M.T.M. Koper. Fourier transform infrared spectroscopy study of CO electro-oxidation on Pt (111) in alkaline media. Langmuir 25, 2009, 13661.

G Garcia, P Rodriguez, S Frank, AA Koverga, M Koper. Electrocatalysis on Well-defined Surfaces. ECS Transactions 25 (1), 203-207

P. Rodriguez, J.M. Feliu and M.T.M. Koper. Unusual adsorption state of carbon monoxide on single-crystalline gold electrodes in alkaline media. Electrochem. Comm.11, 2009, 1105.



N. Garcia-Araez, V. Climent, P. Rodriguez and J.M. Feliu. Thermodynamic analysis of (bi) sulphate adsorption on a Pt (1 1 1) electrode as a function of pH. Electrochimica Acta 53, 2008, 6793.


J. Solla-Gullón, P. Rodríguez, E. Herrero, J. M. Feliu and A. Aldaz. Surface characterization of platinum electrodes. PCCP 10, 2008, 1359.


P. Rodríguez, E. Herrero, J. Solla-Gullón, J. M. Feliu and A. Aldaz. Selective electrocatalysis of acetaldehyde oxime reduction on (111) sites of platinum single crystal electrodes and nanoparticles surfaces. J. Sol. Stat. Electrochem, 12, 2008, 575.



N. García-Aráez, C.L. Brosseau, P. Rodríguez and J. Lipkowski. Layer-by-layer PMIRRAS characterization of DMPC bilayers deposited on a Au (111) electrode surface. Langmuir, 22, 2006, 10365.


P. Rodríguez, E. Herrero, A. Aldaz and J. M. Feliu. Tellurium adatoms as an in-situ surface probe of (111) two-dimensional domains at platinum surfaces. Langmuir 22, 2006, 10329.

J. Solla- Gullón, F.J. Vidal- Iglesias, P.Rodríguez, E. Herrero, J.M. Feliu and A. Aldaz, Shape-dependent electrocatalysis: CO monolayer oxidation at platinum nanoparticles in “Proceedings of the Electrochemical Society: Electrocatalysis,”Vol. 2005-11, ISBN: 1- 56677-436-5, Pennintog, E.E.U.U., , 2006, 1-11.


P. Rodríguez, J. Solla-Gullón, F. Vidal-Iglesias, E. Herrero, A. Aldaz and J. M. Feliu. Determination of (111) ordered domains on platinum electrodes by irreversible adsorption of bismuth. Analytical Chemistry 77, 2005, 5317.


P. Rodríguez, E. Herrero, J. Solla-Gullón, F. Vidal-Iglesias, A. Aldaz and J.M. Feliu. Specific surface reactions for identification of platinum surface domains: Surface characterization and electrocatalytic tests. Electrochimica Acta 50, 2005, 4308.


P. Rodríguez, E. Herrero, J. Solla-Gullón, F. Vidal-Iglesias, A. Aldaz and J.M. Feliu. Electrochemical characterization of irreversibly adsorbed germanium on platinum stepped surfaces vicinal to Pt (1 0 0). Electrochimica Acta 50, 2005, 3111.


F.J. Vidal Iglesias, J. Solla-Gullón, P. Rodríguez, E. Herrero, V. Montiel and J.M. Feliu, Shape-dependent electrocatalysis: ammonia oxidation on platinum nanoparticles with preferential (1 0 0) surfaces. Electrochem. Comm. 6, 2004, 1080.


J. Solla-Gullón, F.J. Vidal-Iglesias, P. Rodríguez, E. Herrero, J.M. Feliu, J. Clavilier and A. Aldaz. In situ surface characterization of preferentially oriented platinum nanoparticles by using electrochemical structure sensitive adsorption reactions. J. Phys. Chem. B.108, 2004, 13573.


C. Borrás, P. Rodríguez, T. Laredo, J. Mostany and B.R. Scharifker.  Electrooxidation of Aqueous p-Methoxyphenol on Lead Oxide Electrodes. J. Appl. Electrochem. 34, 2004, 583.